Sure thing, let's break this down neatly in markdown format:

1. Rewriting CV for this Job Listing

   • Relate your CV to Transport: If you've got any experience related to transport or logistics, highlight them in your CV.
   • Showcase your Safety Record: In my vast experience, employers like the one in this 'jobs in zimbabwe' listing value a good safety record. Point out any driving courses or safety certifications you obtained.
   • Emphasize your Navigation Skills: If you are familiar with GPS or mapping software, this must go on your CV.
   • Communication and Interpersonal Skills: Don't neglect your soft skills. Mention experiences where you have effectively communicated or interacted professionally.
   • Vehicle Maintenance: Your ability to keep a vehicle well-maintained is key. Highlight experiences where you took charge of this, particularly fueling and cleaning duties.

2. Five Key Areas to Note in the Job Listing

   • Deadline: Take note of the application deadline: 15th December 2023. Late submissions don't fare well amongst most Zimbabwean jobs.
   • Application method: Applications must be sent to an email address. Make sure to use a professional email handle.
   • Job Description: This 'job vacancies in Zimbabwe' listing demands brand representation in addition to driving duties. Reflect this understanding in your application and cover letter.
   • Skill Requirements: Highlight the required skills in your CV and cover letter.
   • Who to Report to: The listing specifies reporting to a personal assistant. This can influence your job understanding, as you might be working closely with an executive.

3. Top Three Things to Stand Out

   • Personalized Cover Letter: Show you understand the company's brand and the role you'll play as an ambassador. This can distinguish you from many 'vacancies in zim' applicants.
   • Demonstration of Safety Awareness: In my experience, nothing impresses more in these types of 'job offers in Zimbabwe' than a dedication to safety. Consider sharing a personal anecdote about safety commitment.
   • Testimonies/Recommendations: Strong recommendations, particularly from previous employers, can make you stand out in this 'job search in Zimbabwe'.

4. Potential Misses by First-time Job Seekers

   • Reporting Relationship: Novice applicants often overlook this. But who you report to can dictate your work dynamics.
   • Brand Ambassador Role: First-time applicants might focus too much on the driving and not enough on their role as a company representative.
   • Record Keeping: Keeping mileage and repair records up-to-date might easily be missed by beginners but is essential in such 'employment opportunities in Zimbabwe'.

In conclusion, each 'job vacancies in zim' offers its own unique opportunities and challenges. Be sure to pay attention to detail, tailor your application to the specific listing, and don't underestimate the importance of soft skills. Always remember, vacancies in Zimbabwe are there for those who are willing to understand the needs and nuances of the job before they apply.