Here's the analysis in response to your inquiry:

Tips for Applicants:

1. Chronological CV Structure: From the experience I've gathered, these jobs in Zimbabwe often favor individuals who present their experience in a chronological order, as it gives a clear representation of their growth over the years.
2. Highlighting Experience in admin: As the job description demands an individual who has at least one year of experience in an admin role, it's essential to emphasize any such experiences in your CV extensively.
3. Computer Literacy: It's often forgotten, but for a job like this which requires a high level of computer literacy, specifically mention all your competences with different software or data entry tasks.
4. Relevant Qualifications: Emphasize your most relevant qualifications up front, such as your diploma in Accounting or Business Administration.
5. Showcase Your Skills: In my vast experience, I've noticed that many job vacancies in Zimbabwe, like the one above, desire excellent administrative skills. Ensure that these skills are prominently stated in your CV.

Areas of Greater Note:

1. Application Submission: Pay close attention to the method in which the application is to be submitted. Do adhere to the specific instructions explicitly.
2. Qualification and Experience: Although one year of experience is indicated as a requirement, if you bring substantial value through your skills and knowledge gained from other related roles, this hurdle should not deter your application.
3. Detailed CV: For most vacancies in Zim, the employers put a great premium on the level of detail in the CV. It is advisable to pay heed to this apparently minor detail.
4. Application Marking: The marking "Private and Confidential" should not be missed. The career you wish to land might well hinge on respecting such seemingly trivial requests.
5. Email and Physical Address: Pay due attention to the details when submitting your application.

How to Stand Out:

1. Provide Evidence of Skills: Most applicants will make claims about their skills on their CV, but those who provide clear evidence of their skills are the ones who attract the most attention.
2. Tangible Achievements: Performance indicators are a great way to distinguish your CV from the rest. Including figures or percentages to indicate growth or success in previous roles will make your CV more appealing.
3. Tailored Cover Letter: Complement your CV with a strong cover letter that conveys your passion for this exact role and organization.

From the perspective of the organization:

1. Accounting/Business Administration Diploma: The role clearly emphasizes these two qualifications, a subtlety novice applicants may overlook.
2. Multifaceted Role: The nature of the responsibilities reflects a position that will entail considerable multitasking, requiring an efficient and organized individual.
3. Computer Literacy: The organization is likely heavily digitized, thus any digital skills will be a significant plus.

In my experience, it requires a keen eye to decode such implicit signals. Coupling this with a solid skills set, relevant experience, and the right attitude, even saturated job offers in Zimbabwe can turn into incredible employment opportunities.